本文作者：asymmboy

Chem-station小编继续为学习有机化学的各位同行带来Fukuyama-Yokoshima研究组反应机理问题的详细解答的第十六期。

问题 1

基本文献

[1] K. I. Booker-Milburn, J. K. Cowell, Tetrahedron Lett. 1996, 37, 2177. doi: 10.1016/0040-4039(96)00224-9.

相关链接: 四氧化钌

反应机理

参考文献

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问题 2

基本文献

[1] K. Wada, N. Kogure, M. Kitajima, Takayama, Tetrahedron Lett. 2019, 60, 187. doi: 10.1016/j.tetlet.2018.12.007.

反应机理

参考文献

[1] M. Azuma, T. Yoshikawa, N. Kogure, M. Kitajima, H. Takayama, J. Am. Chem.

Soc. 2014, 136, 11618. doi: 10.1021/ja507016g.

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[4] A. Nakayama, M. Kitajima, H. Takayama, Synlett 2012, 23, 2014. doi: 10.1055/s-0032-1316680.

[5] H. Yang, R. G. Carter, L. N. Zakharov, J. Am. Chem. Soc. 2008, 130, 9238. doi: 10.1021/ja803613w.

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[7] D. A. Evans, J. R. Scheerer, Angew. Chem. Int. Ed. 2005, 44, 6038. doi: 10.1002/anie.200502296.

问题 3

基本文献

[1] S. Tsuchiya, H. Saito, K. Nogi, H. Yorimitsu, Org. Lett..2019, 21, 10, 3855. doi: 10.1021/acs.orglett.9b01353.

相关反应链接

Yorimitsu aromatic metamorphosis reaction

反应机理

参考文献

[1] D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed. 2015, 54, 7162. doi: 10.1002/anie.201501992.

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[3] M. Bhanuchandra, K. Murakami, D. Vasu, H. Yorimitsu, A. Osuka, Angew.

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[5] M. Onoda, Y. Koyanagi, H. Saito, M. Bhanuchandra, Y. Matano, H. Yorimitsu,

Asian J. Org. Chem. 2017, 6, 257. doi: 10.1002/ajoc.201600612.

[6] S. Tsuchiya, H. Saito, K. Nogi, H. Yorimitsu, Org. Lett. 2017, 19, 5557. doi: 10.1021/acs.orglett.7b02660.

[7] H. Saito, S. Otsuka, K. Nogi, H. Yorimitsu, J. Am. Chem. Soc. 2016, 138,

15315. doi: 10.1021/jacs.6b10255.

[8] Y. Kurata, S. Otsuka, N. Fukui, K. Nogi, H. Yorimitsu, A. Osuka, Org. Lett. 2017, 19, 1274. doi: 10.1021/acs.orglett.6b03861.

[9] S. Tsuchiya, H. Saito, K. Nogi, H. Yorimitsu, Org. Lett. 2019, 21, 3855. doi: 10.1021/acs.orglett.9b01353.

[10] Y. Zhou, L. Lin,Y. Wang, J. Zhu, Q. Song, Org. Lett. 2019, 21, 7630. doi: 10.1021/acs.orglett.9b02933.

[11] H. Yorimitsu, D. Vasu, M. Bhanuchandra, K. Murakami, A. Osuka, Synlett

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[12] K. Nogi, H. Yorimitsu, Chem. Commun. 2017, 53, 4055. doi: 10.1039/C7CC00078B.